| publications-721 |
PEER REVIEWED ARTICLE |
2012 |
Boris M. Van Breukelen , Massimo Rolle |
Transverse Hydrodynamic Dispersion Effects on Isotope Signals in Groundwater Chlorinated Solventsâ Plumes |
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10.1021/es301058z |
Simulation & Modeling |
Groundwater |
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No abstract available |
273049 |
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| publications-722 |
PEER REVIEWED ARTICLE |
2013 |
Christina M. Haberer , Massimo Rolle , Olaf A. Cirpka , Peter Grathwohl |
Impact of Heterogeneity on Oxygen Transfer in a Fluctuating Capillary Fringe |
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10.1111/gwat.12149 |
Simulation & Modeling |
Natural Water Bodies |
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AbstractWe performed quasiâtwoâdimensional flow through laboratory experiments to study the effect of a coarseâmaterial inclusion, located in the proximity of the water table, on flow and oxygen transfer in the capillary fringe. The experiments investigate different phases of mass transfer from the unsaturated zone to anoxic groundwater under both steadyâstate and transient flow conditions, the latter obtained by fluctuating the water table. Monitoring of flow and transport in the different experimental phases was performed by visual inspection of the complex flow field using a dye tracer solution, measurement of oxygen profiles across the capillary fringe, and determination of oxygen fluxes in the effluent of the flowâthrough chamber. Our results show significant effects of the coarseâmaterial inclusion on oxygen transfer during the different phases of the experiments. At steady state, the oxygen flux across the unsaturated/saturated interface was considerably enhanced due to flow focusing in the fully waterâsaturated coarseâmaterial inclusion. During drainage, a zone of higher water saturation formed in the fine material overlying the coarse lens. The entrapped oxygenârich aqueous phase contributed to the total amount of oxygen supplied to the system when the water table was raised back to its initial level. In case of imbibition, pronounced air entrapment occurred in the coarse lens, causing oxygen to partition between the aqueous and gaseous phases. The oxygen mass supplied to the anoxic groundwater following the imbibition event was found to be remarkably higher (approximately seven times) in the heterogeneous system compared with a similar experiment performed in a homogeneous porous medium. |
273049 |
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| publications-723 |
PEER REVIEWED ARTICLE |
2014 |
Gabriele Chiogna , Massimo Rolle , Alberto Bellin , Olaf A. Cirpka |
Helicity and flow topology in three-dimensional anisotropic porous media |
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10.1016/j.advwatres.2014.06.017 |
Simulation & Modeling |
Natural Water Bodies |
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No abstract available |
273049 |
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| publications-724 |
PEER REVIEWED ARTICLE |
2012 |
Dominik Eckert , Massimo Rolle , Olaf A. Cirpka |
Numerical simulation of isotope fractionation in steady-state bioreactive transport controlled by transverse mixing |
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10.1016/j.jconhyd.2012.08.010 |
Simulation & Modeling |
Groundwater |
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No abstract available |
273049 |
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| publications-725 |
PEER REVIEWED ARTICLE |
2012 |
Olaf A. Cirpka , Massimo Rolle , Gabriele Chiogna , Felipe P.J. de Barros , Wolfgang Nowak |
Stochastic evaluation of mixing-controlled steady-state plume lengths in two-dimensional heterogeneous domains |
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10.1016/j.jconhyd.2012.05.007 |
Simulation & Modeling |
Groundwater |
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No abstract available |
273049 |
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| publications-726 |
PEER REVIEWED ARTICLE |
2013 |
Christina M. Haberer , Olaf A. Cirpka , Massimo Rolle , Peter Grathwohl |
Experimental Sensitivity Analysis of Oxygen Transfer in the Capillary Fringe |
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10.1111/gwat.12028 |
Simulation & Modeling |
Natural Water Bodies |
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AbstractOxygen transfer in the capillary fringe (CF) is of primary importance for a wide variety of biogeochemical processes occurring in shallow groundwater systems. In case of a fluctuating groundwater table two distinct mechanisms of oxygen transfer within the capillary zone can be identified: vertical predominantly diffusive mass flux of oxygen, and mass transfer between entrapped gas and groundwater. In this study, we perform a systematic experimental sensitivity analysis in order to assess the influence of different parameters on oxygen transfer from entrapped air within the CF to underlying anoxic groundwater. We carry out quasi twoâdimensional flowâthrough experiments focusing on the transient phase following imbibition to investigate the influence of the horizontal flow velocity, the average grain diameter of the porous medium, as well as the magnitude and the speed of the water table rise. We present a numerical flow and transport model that quantitatively represents the main mechanisms governing oxygen transfer. Assuming local equilibrium between the aqueous and the gaseous phase, the partitioning process from entrapped air can be satisfactorily simulated. The different experiments are monitored by measuring vertical oxygen concentration profiles at high spatial resolution with a noninvasive optode technique as well as by determining oxygen fluxes at the outlet of the flowâthrough chamber. The results show that all parameters investigated have a significant effect and determine different amounts of oxygen transferred to the oxygenâdepleted groundwater. Particularly relevant are the magnitude of the water table rise and the grain size of the porous medium. |
273049 |
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| publications-727 |
PEER REVIEWED ARTICLE |
2013 |
Biao Jin , Stefan B. Haderlein , Massimo Rolle |
Integrated Carbon and Chlorine Isotope Modeling: Applications to Chlorinated Aliphatic Hydrocarbons Dechlorination |
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10.1021/es304053h |
Simulation & Modeling |
Groundwater |
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No abstract available |
273049 |
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| publications-728 |
PEER REVIEWED ARTICLE |
2012 |
Christina M. Haberer , Massimo Rolle , Olaf A. Cirpka , Peter Grathwohl |
Oxygen Transfer in a Fluctuating Capillary Fringe |
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10.2136/vzj2011.0056 |
Uncategorized |
Natural Water Bodies |
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No abstract available |
273049 |
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| publications-729 |
PEER REVIEWED ARTICLE |
2014 |
Biao Jin , Massimo Rolle |
Mechanistic approach to multi-element isotope modeling of organic contaminant degradation |
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10.1016/j.chemosphere.2013.08.050 |
Uncategorized |
Groundwater |
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No abstract available |
273049 |
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| publications-730 |
PEER REVIEWED ARTICLE |
2015 |
C. K. Groot , W. B. P. van den Broek , J. Loewenberg , N. Koeman-Stein , M. Heidekamp , W. de Schepper |
Mild desalination of various raw water streams |
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10.2166/wst.2015.228 |
Uncategorized |
Uncategorized |
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For chemical industries, fresh water availability is a pre-requisite for sustainable operation. However, in many delta areas around the world, fresh water is scarce. Therefore, the E4Water project (www.e4water.eu) comprises a case study at the Dow site in Terneuzen, The Netherlands, which is designed to develop commercial applications for mild desalination of brackish raw water streams from various origins to enable reuse in industry or agriculture. This study describes an effective two-stage work process, which was used to narrow down a broad spectrum of desalination technologies to a selection of the most promising techniques for a demonstration pilot at 2â4 mÂł/hour. Through literature study, laboratory experiments and multi-criteria analysis, nanofiltration and electrodialysis reversal were selected, both having the potential to attain the objectives of E4Water at full scale. |
280756 |
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